Zambia is about 2.6 times smaller than Mexico.

Mexico is approximately 1,964,375 sq km, while Zambia is approximately 752,618 sq km, making Zambia 38.31% the size of Mexico. Meanwhile, the population of Mexico is ~129.2 million people (109.5 million fewer people live in Zambia).
This to-scale comparison of Mexico vs. Zambia uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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