Serbia is about 6 times bigger than Montenegro.

Montenegro is approximately 13,812 sq km, while Serbia is approximately 77,474 sq km, making Serbia 461% larger than Montenegro. Meanwhile, the population of Montenegro is ~604,966 people (6.1 million more people live in Serbia).
This to-scale comparison of Montenegro vs. Serbia uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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