Puerto Rico is about 24 times smaller than Guyana.

Guyana is approximately 214,969 sq km, while Puerto Rico is approximately 9,104 sq km, making Puerto Rico 4.24% the size of Guyana. Meanwhile, the population of Guyana is ~789,683 people (2.3 million more people live in Puerto Rico).
This to-scale comparison of Guyana vs. Puerto Rico uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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