Puerto Rico is about 216 times smaller than Mexico.

Mexico is approximately 1,964,375 sq km, while Puerto Rico is approximately 9,104 sq km, making Puerto Rico 0.46% the size of Mexico. Meanwhile, the population of Mexico is ~129.2 million people (126.1 million fewer people live in Puerto Rico).
This to-scale comparison of Mexico vs. Puerto Rico uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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