District of Columbia is about 6,207 times smaller than Bolivia.

Bolivia is approximately 1,098,581 sq km, while District of Columbia is approximately 177 sq km, making District of Columbia 0.02% the size of Bolivia. Meanwhile, the population of Bolivia is ~12.1 million people (11.5 million fewer people live in District of Columbia).
Tip: This to-scale comparison of Bolivia vs. District of Columbia uses the Mercator projection, which distorts the size of regions near the poles.
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