Pennsylvania is about 656 times bigger than District of Columbia.

District of Columbia is approximately 177 sq km, while Pennsylvania is approximately 116,075 sq km, making Pennsylvania 65,479% larger than District of Columbia. Meanwhile, the population of District of Columbia is ~601,723 people (12.1 million more people live in Pennsylvania).
Tip: This to-scale comparison of District of Columbia vs. Pennsylvania uses the Mercator projection, which distorts the size of regions near the poles.