Zambia is about 3,360 times bigger than American Samoa.

American Samoa is approximately 224 sq km, while Zambia is approximately 752,618 sq km, making Zambia 335,890% larger than American Samoa. Meanwhile, the population of American Samoa is ~45,443 people (19.6 million more people live in Zambia).
This to-scale comparison of American Samoa vs. Zambia uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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