Ukraine is about 6 times bigger than South Korea.

South Korea is approximately 99,720 sq km, while Ukraine is approximately 603,550 sq km, making Ukraine 505% larger than South Korea. Meanwhile, the population of South Korea is ~51.8 million people (8.3 million fewer people live in Ukraine).
This to-scale comparison of South Korea vs. Ukraine uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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