Ukraine is about 1.5 times smaller than Nigeria.

Nigeria is approximately 923,768 sq km, while Ukraine is approximately 603,550 sq km, making Ukraine 65.34% the size of Nigeria. Meanwhile, the population of Nigeria is ~225.1 million people (181.6 million fewer people live in Ukraine).
This to-scale comparison of Nigeria vs. Ukraine uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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