Pennsylvania is about 1,903 times bigger than San Marino.

San Marino is approximately 61 sq km, while Pennsylvania is approximately 116,075 sq km, making Pennsylvania 190,187% larger than San Marino. Meanwhile, the population of San Marino is ~34,682 people (12.7 million more people live in Pennsylvania).
Tip: This to-scale comparison of San Marino vs. Pennsylvania uses the Mercator projection, which distorts the size of regions near the poles.