Papua New Guinea is about 3.8 times bigger than Mississippi.

Mississippi is approximately 121,489 sq km, while Papua New Guinea is approximately 462,840 sq km, making Papua New Guinea 281% larger than Mississippi. Meanwhile, the population of Mississippi is ~3.0 million people (6.6 million more people live in Papua New Guinea).
This to-scale comparison of Mississippi vs. Papua New Guinea uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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