Louisiana is around the same size as Liberia.

Liberia is approximately 111,369 sq km, while Louisiana is approximately 112,825 sq km, making Louisiana 1% larger than Liberia. Meanwhile, the population of Liberia is ~5.7 million people (1.1 million fewer people live in Louisiana).
Tip: This to-scale comparison of Liberia vs. Louisiana uses the Mercator projection, which distorts the size of regions near the poles.
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