Illinois is about 4.2 times smaller than Ukraine.

Ukraine is approximately 603,550 sq km, while Illinois is approximately 143,961 sq km, making Illinois 23.85% the size of Ukraine. Meanwhile, the population of Ukraine is ~43.5 million people (30.7 million fewer people live in Illinois).
This to-scale comparison of Ukraine vs. Illinois uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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