Ecuador is about 3.9 times smaller than Bolivia.

Bolivia is approximately 1,098,581 sq km, while Ecuador is approximately 283,561 sq km, making Ecuador 25.81% the size of Bolivia. Meanwhile, the population of Bolivia is ~12.1 million people (5.2 million more people live in Ecuador).
This to-scale comparison of Bolivia vs. Ecuador uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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