Democratic Republic of the Congo is about 258 times bigger than Puerto Rico.

Puerto Rico is approximately 9,104 sq km, while Democratic Republic of the Congo is approximately 2,344,858 sq km, making Democratic Republic of the Congo 25,656% larger than Puerto Rico. Meanwhile, the population of Puerto Rico is ~3.1 million people (105.3 million more people live in Democratic Republic of the Congo).
This to-scale comparison of Puerto Rico vs. Democratic Republic of the Congo uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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