Chile is about 1.2 times bigger than Ukraine.

Ukraine is approximately 603,550 sq km, while Chile is approximately 756,102 sq km, making Chile 25% larger than Ukraine. Meanwhile, the population of Ukraine is ~43.5 million people (25.1 million fewer people live in Chile).
This to-scale comparison of Ukraine vs. Chile uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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