Chile is about 2.2 times bigger than Republic of the Congo.

Republic of the Congo is approximately 342,000 sq km, while Chile is approximately 756,102 sq km, making Chile 121% larger than Republic of the Congo. Meanwhile, the population of Republic of the Congo is ~5.5 million people (12.9 million more people live in Chile).
This to-scale comparison of Republic of the Congo vs. Chile uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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