Armenia is about 20 times smaller than Ukraine.

Ukraine is approximately 603,550 sq km, while Armenia is approximately 29,743 sq km, making Armenia 4.93% the size of Ukraine. Meanwhile, the population of Ukraine is ~43.5 million people (40.5 million fewer people live in Armenia).
This to-scale comparison of Ukraine vs. Armenia uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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