American Samoa is about 2.2 times bigger than Montserrat.

Montserrat is approximately 102 sq km, while American Samoa is approximately 224 sq km, making American Samoa 120% larger than Montserrat. Meanwhile, the population of Montserrat is ~5,414 people (40,029 more people live in American Samoa).
This to-scale comparison of Montserrat vs. American Samoa uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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