Rio De Janeiro is about 2.1 times smaller than Moscow.

Moscow (map shows its 125 districts within the pre-2012 boundary; the area includes New Moscow) is approximately 2,562 sq km, while Rio De Janeiro is approximately 1,221 sq km, making Rio De Janeiro 47.67% the size of Moscow.
Tip: This to-scale comparison of Moscow vs. Rio De Janeiro uses the Mercator projection, which distorts the size of regions near the poles.
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