Niger is about 490 times bigger than Luxembourg.

Luxembourg is approximately 2,586 sq km, while Niger is approximately 1,267,000 sq km, making Niger 48,895% larger than Luxembourg. Meanwhile, the population of Luxembourg is ~650,364 people (23.8 million more people live in Niger).
This to-scale comparison of Luxembourg vs. Niger uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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