Bolivia is about 1.2 times bigger than Venezuela.

Venezuela is approximately 912,050 sq km, while Bolivia is approximately 1,098,581 sq km, making Bolivia 20% larger than Venezuela. Meanwhile, the population of Venezuela is ~29.8 million people (17.7 million fewer people live in Bolivia).
This to-scale comparison of Venezuela vs. Bolivia uses the Mercator projection, which distorts the size of regions near the poles. Learn more.

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